单原子催化剂电催化氧还原产过氧化氢研究进展

doi:10.16180/j.cnki.issn1007-7820.2022.11.013

Abstract

Abstract:

Hydrogen peroxide production via electrocatalytic two-electron oxygen reduction is an effective alternative to traditional centralized anthraquinone processes. However, this process depends on a catalyst with low cost, high activity and high selectivity. In recent years, SACs have been considered as potential catalysts for oxygen reduction and hydrogen peroxide production due to their nearly 100% atom utilization efficiency, tunable electronic structure, and excellent catalytic performance, but the regulation of SAC activity remains a challenge. Starting from the mechanism of the ORR, the influence of the binding strength of the active metal center and *OOH on the oxygen reduction reaction pathway is elucidated. This study systematically illustrates the effect of adjusting the structure of the SAC on the binding of the metal center to *OOH from three aspects: metal center atom, coordination atom and the surrounding environment of the active center, and reveals the activity and selectivity of H₂O₂ production.

Key words: electrocatalysis, oxygen reduction reaction, hydrogen peroxide, activity, selectivity, single-atom catalyst, *OOH intermediate, structure regulation

CLC Number:

TN948.64

JIN Tao,HU Xia,YU Lanlan,ZHAO Wenjun,YANG Qi,TUO Ya. Progress in Electrocatalysis Oxygen Reduction for Hydrogen Peroxide Production over Single-Atom Catalysts[J].Electronic Science and Technology, 2022, 35(11): 90-97.

Figures/Tables 6

Figure 1.

Figure 2.

Figure 3.

Figure 4.

Figure 5.

Table 1.

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单原子催化剂	金属负载量	选择性或产率	电解液	参考文献
Co-N-C	0.56 at%	90.9mmol·g^-1 cat·h^-1, 80%	0.5 mol·L^-1 H₂SO₄	[20]
Co-N-C and OFGs	0.60 at%	2.98 mg·cm^-2·h^-1, 80%	0.1 mol·L^-1 KOH	[38]
Surface-oxidized M-N-C (M = Fe, Co, Mn)	1.40 wt%	30~87%	0.1 mol·L^-1 HClO₄	[39]
Fe-C-O	0.10 at%	95%	0.1 mol·L^-1 KOH	[26]
Co-N4(O)-C	1.40 wt%	418± 19 mmol·g^-1 cat·h^-1	0.1 mol·L^-1 KOH	[34]
Mo-O₃S-C	13.47 wt%	95%	0.1 mol·L^-1 KOH	[31]
Ni-N₂O₂-C	2.00 wt%	5.9 mol·g^-1·h^-1, 96%	0.1 mol·L^-1 KOH	[30]
C@C₃N₄-Pa	0.50 wt%	94%	0.1 mol·L^-1 HClO₄	[29]

Progress in Electrocatalysis Oxygen Reduction for Hydrogen Peroxide Production over Single-Atom Catalysts

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